A summary of the extensive work done on the paper Constituents of Cannabis Sativa L XVII, A Review of the Natural Constituents, by Turner, Elsohly, and Boeren at the Research Institute of Pharmaceutical Sciences, School of Pharmacy,
University of Mississippi.
Dr. Fischedick was kind enough to provide me with a copy of a paper done at Old Miss, as part of my research on the THC and CBN cycles. A lengthy tome, which details the 421 compounds they found in Sweet Mary, ranging from our beloved cannabinoids, terpenes, and flavonoids, to alkaloids and Alkane hydrocarbons.
To say that I was blown away, would be an understatement, and puts new meaning to the term “Whole Plant Extract.”
ASP Publications can provide the whole article at: http://pubs.acs.org/doi/abs/10.1021/np50008a001
For those of ya’ll looking for an arms around view, check out the following table that I whomped up from their excellent work:
COMPOUNDS IN SWEET MARY | ||
NO | COMPOUND | QTY |
1.0 Cannabinoids | ||
1.1 | Cannabigerol (CBG) type | 6 |
1.1.1 | Cannabigerolic acid | |
1.1.2 | Cannabigerolic acid monomethylether | |
1.1.3 | Cannabigerol | |
1.1.4 | Cannabigerol monomethylether | |
1.1.5 | Cannabigerovarinic acid | |
1.1.6 | Cannabigerovarin | |
1.2 | Cannabichromene (CBC) type | 4 |
1.2.1 | Cannabichromenic acid | |
1.2.2 | Cannabichromene | |
1.2.3 | Cannabichromevarinic acid | |
1.2.4 | Cannabichromevarin | |
1.3 | Cannabidiol (CBD) type | 7 |
1.3.1 | Cannabidiolic acid | |
1.3.2 | Cannabidiol | |
1.3.3 | Cannabidiol monomethylether | |
1.3.4 | Cannabinidiol-c-4 | |
1.3.5 | Cannabidivarinic acid | |
1.3.6 | Cannavidivarin | |
1.3.7 | Cannabvidiorcol | |
1.4 | D9-Tetrahydrocannabinol (d9-THC) type | 9 |
1.4.1 | d-9-(trans)-Tetrahydrocannabonolic acid A | |
1.4.2 | d-9-(trans)-Tetrahydrocannabonolic acid B | |
1.4.3 | d-9-(trans)-Tetrahydrocannabinol | |
1.4.4 | d-9-(trans)-Tetrahydrocannabonolic acid-C4 | |
1.4.5 | d-9-(trans)-Tetrahydrocannabinol-C-4 | |
1.4.6 | d-9-(trans)-Tetrahydrocannabivarinic acid | |
1.4.7 | d-9-(trans)-Tetrahydrocannabivarin | |
1.4.8 | d-9-(trans)-Tetrahydrocannabiorcolic acid | |
1.4.9 | d-9-(trans)-Tetrahydrocannabiorcol | |
1.5 | D8 Tetrahydrocannabinol (d8-THC) type | 2 |
1.5.1 | d-8(trans)-Tetrahydrocannabinolic acid | |
1.5.2 | d-8(trans)-Tetrahydrocannabinol | |
1.6 | Cannabicyclol (CBL) type | 3 |
1.6.1 | Cannabicyclolic acid | |
1.6.2 | Cannabicyclo | |
1.6.3 | Cannavicclovarin | |
1.7 | Cannabielsoin (CBE) type | 3 |
1.7.1 | Cannabielsoic acid A | |
1.7.2 | Cannabielsoic acid B | |
1.7.3 | Cannabielsoin | |
1.8 | Cannabinol (CBN) type | 6 |
1.8.1 | Cannabinolic acid | |
1.8.2 | Cannabinol | |
1.8.3 | Cannabinol methylether | |
1.8.4 | Cannabinol-C-4 | |
1.8.5 | Cannabivarin | |
1.8.6 | Cannabiorcol | |
1.9 | Cannabinodiol (CBND) type | 2 |
1.9.1 | Cannabinodiol | |
1.9.2 | Cannabinodivarin | |
1.10 | Cannabitriol (CBT) type | 6 |
1.10.1 | (-) Cannabitriol | |
1.10.2 | (+) Cannabitriol | |
1.10.3 | 9-10-ethoxy-9-hydroxy-d6 tetrahydrocannabinol | |
1.10.4 | 10-ethoxy-9-hydroxy-d6-tetrahydrocannabinol | |
1.10.5 | 8-9-dihydroxy-d6-tetrahydrocannabinol | |
1.10.6 | Cannabidiolic acid tetrahydrocannabitriol ester (CBD-THO)(CBDA ester at 9-OH group | |
1.11 | Misc cannabinoids -Recently added | 4 |
1.11.1 | Cannabichromanone-C3 | |
1.11.2 | Cannabielsoin-C3 | |
1.11.2 | Cannabielsoin acid B-C3 | |
1.11.4 | Cannabicumaronone | |
1.12 | Miscellaneous types | 9 |
1.12.1 | Dehydrocannabifuran | |
1.12.2 | Cannabifuran | |
1.12.3 | Cannabichromanon | |
1.12.4 | Cannabicitran | |
1.12.5 | 10-Oxo-d6 Tetrahydrocannabinol | |
1.12.6 | D9-(6a, 10a, cis)-Tetrahydrocannabinol | |
1.12.7 | 3,4,5,6-Tetrahydro-7-hydroxy-2-trimethyl-9-n-propyl-2-6-methano-2H-1-benzoxocin-5-methanol | |
1.12.8 | (-)=(6aR,9S,10S,10aR)-9,10-Dihydroxyhexa-hydrocannabinol [Cannabiripsol] | |
1.12.9 | 6a,7.10a-Trihydroxy d9-tetrahydrocannabinol | |
2.0 Nitrogenous Compounds | 20 | |
2.1 | Quaternary bases | 5 |
2.1.1 | Choline | |
2.1.2 | Trigonelline | |
2.1.3 | Muscarinew | |
2.1.4 | L-(+) isoleucine betaine | |
2.1.5 | Neurine | |
2.1 | Amides | 1 |
2.1.1 | N-(p-hydroxy-b-phenylethyl)-p-hydroxy-(trans)-cinnamide | |
2.2 | Amines | 12 |
2.2.1 | Piperidine | |
2.2.2 | Hordenine | |
2.2.3 | Amonia | |
2.2.4 | Methylamine | |
2.2.5 | Ethylamine | |
2.2.6 | n-propylamine | |
2.2.7 | n-Butylamine | |
2.2.8 | Iso-butylamine | |
2.2.9 | Sebutylamine | |
2.2.10 | Dimethylamine | |
2.2.11 | Diethylamine | |
2.2.12 | Pyrrolidine | |
2.3 | Spermidine alkaloids | 2 |
2.3.1 | Cannabisativine | |
2.3.2 | Anhydrocannabisatacvine | |
3.0 Amino Acids | 18 | |
3.1 | Alanine | |
3.2 | Asparic acid | |
3.3 | Cystine | |
3.4 | Glutamic acid | |
3.5 | Glycene | |
3.6 | Serine | |
3.7 | Arginine | |
3.8 | Histidine | |
3.9 | Isoleucine | |
3.10 | Leucine | |
3.11 | Lycine | |
3.12 | Mtthionine | |
3.13 | Phenylalanine | |
3.14 | Proline | |
3.15 | Threonine | |
3.16 | Tryptophane | |
3.17 | Tyrosine | |
3.18 | Valine | |
4.0 Proteins, glycoproteins, and enzymes | 9 | |
4.1 | Edestin | |
4.2 | Zeatin | |
4.3 | Zeatin nucleoside | |
4.4 | Edestinase | |
4.5 | Glucosidase (emulsin) | |
4.6 | Polyphenol oxidase | |
4.7 | Peptidase (ereptase) | |
4.8 | Peroxidase | |
4.9 | Adenosine-5-Phosphatase | |
5.0 Sugars and related compounds | 34 | |
5.1 | Mosaccharides | 13 |
5.1.1 | Arabinose | |
5.1.2 | Frutose | |
5.1.3 | Galactose | |
5.1.4 | Galacturonic acid | |
5.1.5 | a-D-glucose | |
5.1.6 | b-D-glucose | |
5.1.7 | Altro-Heptulose (sedo-heptulose) | |
5.1.8 | D-mano-heotulose | |
5.1.9 | Mannose | |
5.1.10 | D-glycerol-D-manno-Octulose | |
5.1.11 | Rhamnose | |
5.1.12 | Ribose | |
5.1.13 | Xylose | |
5.2 | Disaccharides | 2 |
5.2.1 | Sucrose (saccharose) | |
5.2.2 | Maltose | |
5.3 | Polysaccharides | 5 |
5.3.1 | Raffinose (oligosaccharide) | |
5.3.2 | Cellulose | |
5.3.3 | Hemicellulose | |
5.3.4 | Pectin | |
5.3.5 | Xylan | |
5.4 | Cyclitols | 12 |
5.4.1 | Arabitol (arabinitol) | |
5.4.2 | Erythritol | |
5.4.3 | Galactitol | |
5.4.4 | Glycerol | |
5.4.5 | Mannitol | |
5.4.6 | Ribitol | |
5.4.7 | Sorbitol | |
5.4.8 | Xylitol | |
5.4.9 | D (-) Bornesitol | |
5.4.10 | (+) Inositol | |
5.4.11 | Myo-Inositol | |
5.4.12 | (+) Quebrachitol (1L-2-O-methyl-chiro-inositol | |
5.5 | Aminosugars | 2 |
5.5.1 | Galactosamine | |
5.5.2 | Glucosamine | |
6.0 Hydrocarbons | 50 | |
6.1 | C9H20 n-Nonane | |
6.2 | C10H22 n-Decane | |
6.3 | C11H24 n-Undecane | |
6.4 | C12H26 n-Dodecane | |
6.5 | C13H25 n-Tridecane | |
6.6 | C14H30 n-Tetradecane | |
6.7 | C15H32 3,6-Dimethyl-tridecane | |
6.8 | C15H32 n-Pentadecane | |
6.9 | C16H34 2,6-Dimethyl-tetradecane | |
6.10 | C16H34 n-Hexadecane | |
6.11 | C17H36 n-Heptadecane | |
6.12 | C18H38 2,6-Dimethyl-hexadecane | |
6.13 | C18H38 n-Octadecane | |
6.14 | C19H40 3,6-Dimethyl-heptadecane | |
6.15 | C19H40 3,7-Dimethyl-heptadecane | |
6.16 | C19H40 n-Nonadecane | |
6.17 | C20H42 3,6-Dimethyl-octadecane | |
6.18 | C20H42 3,7-Dimethyl-octadecane | |
6.19 | C20H42 n-Eicosane | |
6.20 | C21H44 n-Heneicosane | |
6.21 | C22H46 3-Methyl-heneicosane | |
6.22 | C22H46 n-Docosane | |
6.23 | C23H48 n-Tricosane | |
6.24 | C24H50 3-Methyl-tricosane | |
6.25 | C24H50 n-Tetrasane | |
6.26 | C25H52 2-Methyl-tetrasane | |
6.27 | C-25H52 n-Pentacosane | |
6.28 | C26H54 n-Hexacosane | |
6.29 | C26H54 3-Methyl-pentacosane | |
6.30 | C27H56 2-Methyl-hexacosane | |
6.31 | C27H56 n-Heptacosane | |
6.32 | C28H58 n-Octacosane | |
6.33 | C29H60 2-Methyl-octacosane | |
6.34 | C29H60 9-Methyl-octacosane | |
6.35 | C29H60 n-Nonacosane | |
6.36 | C31H64 3-Methyl-triacontane | |
6.37 | C30H62 n-Triacontane | |
6.38 | C32H66 2-Methyl-hentriacontane | |
6.39 | C31H64 n-Hentriacontane | |
6.40 | C32H66 3-Methyl-hentriacontane | |
6.41 | C32H66 n-Dotriacontane | |
6.42 | C33H68 2-Methyl-dotriacontane | |
6.43 | C33H68 n-Tritracontane | |
6.44 | C34H70 Tetra-triacaontane | |
6.45 | C35H72 Pentatriacontane | |
6.46 | C36H74 Hexatriacontane | |
6.47 | C37H76 Heptatriacontane | |
6.48 | C38H78 Octatriacontane | |
6.49 | C39H80 Nonatriacontane | |
6.50 | ||
7.0 Simple Alcohols | 7 | |
7.1 | Methanol | |
7.2 | Ethanol | |
7.3 | 1-Octene-3-01 | |
7.4 | Octanol-1 | |
7.5 | Octanol-3 | |
7.6 | Nonanol-1 | |
7.7 | Hexadecanol-1 | |
8.0 Simple Aldehydes | 12 | |
8.1 | Acetaldehyde | |
8.2 | Isobutyraldehyde | |
8.3 | Pentanal | |
8.4 | Hexanal | |
8.5 | Heptanal | |
8.6 | Octanal | |
8.7 | Nonanal | |
8.8 | Decanal | |
8.9 | Undecanal | |
8.10 | Dodecanal | |
8.11 | Tridecanal | |
8.12 | p-Ethylbenzaldehyde | |
9.0 Simple Ketones | 13 | |
9.1 | Acetone | |
9.2 | Heptanone-2 | |
9.3 | 2-Methyl-2-heptene-6-one | |
9.4 | Decanone-2 | |
9.5 | Undecanone-2 | |
9.6 | Dodecanone-2 | |
9.7 | Pentadecanone-2 | |
9.8 | Octanone-3 | |
9.9 | 2,2,6-Trimethyl cyclohexanone | |
9.10 | 2,2,6-Trimethyl-5-cyclohexenone | |
9.11 | 3-Decene-5-one | |
9.12 | 6,10-Dimethyl undecanone-2 | |
9.13 | 6,10,14-Trimethyl pentadecanone-2 | |
10.0 Simple Acids | 20 | |
10.1 | Arabinic | |
10.2 | Azelaic | |
10.3 | Trans-Cinnamic | |
10.4 | Citric | |
10.5 | Glucaric | |
10.6 | Gluconic | |
10.7 | Glyceric | |
10.8 | p-Hydroxybezoic | |
10.9 | p-Hydroxycinnamic (p-Coumaric) | |
10.10 | Isocritic | |
10.11 | Malic | |
10.12 | Malonic | |
10.13 | 2-C-Methylaldotetronic | |
10.14 | 3-Methoxy-4-hydroxycinnamic (Ferulic) | |
10.15 | Phosphoric | |
10.16 | Pyroglutamic | |
10.17 | Quinic | |
10.18 | Succinic | |
10.19 | Threonic | |
10.20 | Vanillic | |
11.0 Fatty Acids | 12 | |
11.1 | Arachidic | |
11.2 | Behenic | |
11.3 | Eicosadienic | |
11.4 | Eicosemic | |
11.5 | Linoleic | |
11.6 | Linolenic | |
11.7 | Myristic | |
11.8 | Oleic | |
11.9 | Palitoleic | |
11.10 | Palmitoleic | |
11.11 | Sativic | |
11.12 | Stearic | |
12.0 Simple esters and lactones | 13 | |
12.1 | Benzyl acetate | |
12.2 | p-Ethyl benzyl acetate | |
12.3 | Cis-3-Hexenyl caproate | |
12.4 | Hexyl acetate | |
12.5 | Hexyl butyrate | |
12.6 | Hexyl caproate | |
12.7 | Hexyl Isobutyrate | |
12.8 | Methl acetate | |
12.9 | 2-C-Methyl-aldotetronolact one | |
12.10 | Methyl linoleate | |
12.11 | Methyl palmitate | |
12.12 | Methyl salicylate | |
12.13 | Octyl caproate | |
13.0 Steroids | 11 | |
13.1 | Campesterol | |
13.2 | Campest-5-en-3b-ol-7-one | |
13.3 | Campest-4-en-3-one | |
13.4 | Ergosterol | |
13.5 | b-Sitosterol | |
13.6 | 5-Stigmast a-7, 24(28)-dien-3b-ol | |
13.7 | Stigmasta-5,22-dien-3b-ol-7-one | |
13.8 | Stigmasta-4, 22-dien-3-one | |
13.9 | Stigmast-5-en-3b-ol-7-one(7-Keto-b-sitosterol) | |
13.10 | Sigmast-4-en-3-one | |
13.11 | Stigmastaterol | |
14.0 Terpenes | 103 | |
14.1 | Monoterpenes | 58 |
14.1.1 | Borneol | |
14.1.2 | Bornyl acetate | |
14.1.3 | Camphene | |
14.1.4 | Camphenehydrate | |
14.1.5 | Camphor | |
14.1.6 | d-8 Carene | |
14.1.7 | d-4 Carene | |
14.1.8 | Carvacrol | |
14.1.9 | Carvone | |
14.1.10 | b-Cyclocitral | |
14.1.11 | 1,4-Cineol | |
14.1.12 | 1,8-Cineol | |
14.1.13 | Citral B | |
14.1.14 | Citronellol | |
14.1.15 | p-Cymene | |
14.1.16 | p-Cymene-8-ol | |
14.1.17 | Dihydrocarveyl acetate | |
14.1.18 | Dihydrocarvone | |
14.1.19 | Fenchyl alcohol | |
14.1.20 | Fenchone | |
14.1.21 | Geraniol | |
14.1.22 | Geranyl acetone | |
14.1.23 | Limonene | |
14.1.24 | Linalool | |
14.1.25 | cis-Linalool oxide | |
14.1.26 | trans-Linalool oxide | |
14.1.27 | m-Metha-1,8(9)-dien-5-ol | |
14.1.28 | 1-Mentha-1-4-iso-propenylbenzene | |
14.1.29 | Myrcene | |
14.1.30 | Nerol | |
14.1.31 | Nerolidol | |
14.1.32 | Cis-b-Ocimene | |
14.1.33 | Perillene | |
14.1.34 | a-Phellandrene | |
14.1.35 | b-Phellandrene | |
14.1.36 | 3-Phenyl-2-Methyl-prop-1-ene | |
14.1.37 | a-Pinene | |
14.1.38 | b-Pinene | |
14.1.39 | a-Pinene oxide | |
14.1.40 | Pinocarveol | |
14.1.41 | Pinocarvone | |
14.1.42 | Piperitenone | |
14.1.43 | Piperitone oxide | |
14.1.44 | Piperitenone oxide | |
14.1.45 | Pulegone | |
14.1.46 | Sabinene | |
14.1.47 | trans-Sabinene hydrate | |
14.1.48 | Sabinol | |
14.1.49 | Safranal | |
14.1.50 | a-Thujene | |
14.1.51 | a-Terpinene | |
14.1.52 | y-Terpinene | |
14.1.53 | a-Terpinene-4-ol | |
14.1.54 | a-Terpinolene | |
14.1.55 | a-Terpineol | |
14.1.56 | Thujyl alcohol | |
14.1.57 | ||
14.1.58 | ||
14.2 | Sesquiterpenes | 38 |
14.2.1 | Allo-aromadendrene | |
14.2.2 | a-trans-Bergamotene | |
14.2.3 | b-Bisabolene | |
14.2.4 | a-Bisabolol | |
14.2.5 | Calamene | |
14.2.6 | Caryophyllene | |
14.2.7 | a-Caryophyllene (Humulene) | |
14.2.8 | b-Caryophyllene | |
14.2.9 | Iso-Caryophyllene | |
14.2.10 | a-Caryophyllene alcohol (Caryophyllene epoxide) | |
14.2.11 | a-Cedrene | |
14.2.12 | y-Cadinene | |
14.2.13 | b-Cadinene | |
14.2.14 | a-Copaene | |
14.2.15 | a-Cubenbene | |
14.2.16 | a-Curcumene | |
14.2.17 | y-Elemene | |
14.2.18 | y-Eudesmol | |
14.2.19 | b-Farnesene | |
14.2.20 | (Z)-b-Farnesene | |
14.2.21 | trans-trans-a-Farnesene | |
14.2.22 | Farnesol | |
14.2.23 | Farnesyl Acetone | |
14.2.24 | a-Gurjunene | |
14.2.25 | Guaiol | |
14.2.26 | b-Humulene | |
14.2.27 | Humulene epoxide I | |
14.2.28 | Humulene epoxide II | |
14.2.29 | Ledol | |
14.2.30 | Longifolene | |
14.2.31 | Nerolidol | |
14.2.32 | Epi-b-Santalene | |
14.2.33 | a-Selinene | |
14.2.34 | b-Selinene | |
14.2.35 | Selina-3,7(11)-diene | |
14.2.36 | Selina-4(14),7(11)-diene | |
14.2.37 | ||
14.2.38 | ||
14.3 | Diterpenes | 1 |
14.3.1 | Phytol | |
14.4 | Triterpenes | 2 |
14.4.1 | Friedelin (Friedelan-3-one) | |
14.4.2 | Epifriedelanol | |
14.5 | Misc compounds of terpene origin | 4 |
14.5.1 | Vomifoliol (blumenol A) | |
14.5.2 | Dihydrovomifoliol (blumenol B) | |
14.5.3 | b-Ionone | |
14.5.4 | Dihydroactinidiolide | |
15.0 Non cannabinoid phenols | 16 | |
15.1 | Acetylcannaispirol | |
15.2 | Cannabispiradienone | |
15.3 | b-Cannabispiranol (cannaispirol) | |
15.4 | Cannabispirenone (Dehydrocannavispiran) | |
15.5 | Cannabispirenone-isomer | |
15.6 | Cannabispirone (Cannabispiran) | |
15.7 | 3-[2-(4-hydroxyphenyl) ethyl]-5-Methoxyphenol | |
15.8 | 3-[2-(3-hydroxy-4-methoxyphenyl) ethyl]-5-methoxyphenol | |
15.9 | 3-[2-(3-isoprenyl-4-hydroxy-5-methoxy-phenyl) ethyl]-5-methoxyphenol | |
15.10 | 3-[2-(2-isoprenyl-3-hydroxy-4-methoxyphenyl)ethyl]-5-methoxyphenol (canniprene) | |
15.11 | Cannabidihydrophenanthrene | |
15.12 | Eugenol | |
15.13 | iso-Eugenol | |
15.14 | cis-Antethol | |
15.15 | trans-Anethol | |
15.16 | Methyleugenol | |
16.0 Flavanoidglycosides | 19 | |
16.1 | Apigenin-7-O-p-coumarylglucoside | |
16.2 | Apiginin-7-O-glucoside (Cosmosioside) | |
16.3 | Apigenin-O-glucoside | |
16.4 | Isovitexin-7-O-Glucoarabinoside | |
16.5 | Isovitexin-O-glucoside | |
16.6 | Isovitexin-7-rhamnoglucoside | |
16.7 | Kaempferol-O-glycoside(s) | |
16.8 | Luteolin-O-glucoside | |
16.9 | Orientin | |
16.19 | Orientin-7-O-glucoside | |
16.11 | Orientin-O-glucoside | |
16.12 | Orientin-7-O-rhamnoglucoside | |
16.13 | Quercetin-O-glucoside(s) | |
16.14 | Vitexin-7-O-(6″-glucoside) | |
16.15 | Vitexin-O-glucoside | |
16.16 | Vitexin-O-rhamnoglucoside | |
16.17 | 2″-O-Glucopyranosylorientin | |
16.18 | 2″-O-glucopyranosylvitexin | |
16.19 | ||
. | ||
17.0 Vitamins | 1 | |
17.1 | Vitamin K | |
18.0 Pigments | 2 | |
18.1 | Carotene | |
18.2 | Zanthophylls | |
19.0 Total Compounds | 421 |